Gasification is a well-known technology and new applications are fueled as a replacement for fossil fuels with renewable energy sources to reduce CO2 emissions. Syngas generated by gasification contains impurities which will impede direct use. Impurities can cause severe problems to operating facilities. Corrosion, fouling, clogging of instrumentation, damage and tarring of machinery are serious problems that can lead to accidents and downtime. Main pollutions in the syngas to be eliminated with a scrubber can be classified as:
Depending on the kind of biomass used other components could originate or being released.
There are several methods to improve the syngas to comply the necessary requirements. This article deals with wet gas scrubbing technology which decrease the amount of impurities in the syngas to use it for instance in combustion engines or methanization systems. The syngas is contaminated and has a high discharge temperature (< 800°C).
Operators of gasification systems focus regularly on tar elimination, polycyclic aromatic hydrocarbons (PAHs) reduction and fine dust particulate removal (ash and soot). The objective of Lechler is to investigate tar elimination, which is a mixture of heavier hydrocarbons and compounds. Water and an organic liquid (solvent) predominantly have to be applied for tar and PAHs elimination from syngas.
Nowadays rapeseed methyl ester and biodiesel appear to be more environmentally friendly, are the most common organic liquids, sometimes used in combination with alcohols.
How an FTIR works
Molecules that have a sufficiently large dipole moment absorb infrared light. The absorbed energy is converted into a movement between the different atoms in the molecule. The degree of absorption depends on the number of atoms in the molecule and the type of bond between the atoms. Depending on the characteristics of each molecule, there are multiple frequencies in the infrared spectrum where the molecules absorb the energy of infrared light. If multiple components are present in the gas mixture (both known and unknown), Fourier Transform Infrared (FTIR) is an accurate technique to identify and quantify all infrared-absorbing components. The software of our Gasmet FTIR analyzers is capable of analyzing up to 50 components in real time. This is in contrast to NDIR which looks at one wavelength.
Light
An FTIR spectrophotometer works according to the following principles: light with frequencies from almost the entire IR spectrum is simultaneously sent onto a semi-transparent mirror. Half of the light is not reflected and travels straight ahead, and the other half is reflected at a 90-degree angle. The light is then reflected on the first mirror or on the movable second mirror. The position of this second mirror is accurately determined using a laser.
Reinforcement and extinction
The light has now traveled two distances from its origins. After reflection, the light rays arrive at the semi-permeable mirror and interfere here. Light interference is the process by which two or more light waves come together to form a light pattern. The light is sent through the medium to be measured and forms an interference pattern that is received on a detector.
Calcmet en Gasmet
In the interferogram, the position of the second mirror is plotted against the measured intensity on the detector. A numerical Fourier transform is used to determine which waves (frequency and amplitude) make up the interferogram. This data is displayed graphically in the transmission spectrum. This shows the frequency of the wave versus the amplitude.
Each molecule has a unique transmission spectrum. The total transmission spectrum is made up of the different transmission spectra of the individual molecules. Gasmet's Calcmet™ software contains a very extensive library (a growing collection of approximately 5000 transmission spectra) and is able to determine via a numerical algorithm which molecules make up the total transmission spectrum.
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