Carbon Dioxide — properties & hazards overview

Name: Carbon dioxide Formula: CO₂ CAS: 124-38-9 UN: 1013 (compressed) / 2187 (refrigerated liquid)
WARNING — Non-flammable and non-toxic in the classical sense, but a simple asphyxiant that is 1.5× heavier than air and collects in sumps, pits and duct low points. In a caustic scrubber CO₂ is the hidden consumer of NaOH: it reacts before your target acid gas does.
Sublimation point
−78.5 °C (1 atm)
Vapour density
1.98 g/L (0 °C) — 1.5× air
Water solubility
1.7 g/L (20 °C), forms H₂CO₃
Flammability
Non-flammable (inert)
Toxicity
Asphyxiant above ~4 vol%
Flammability
Non-flammable
Chronic risk
No chronic toxicity
Environmental
Greenhouse gas
PropertyValue / Note
Chemical formulaCO₂
Molar mass44.01 g/mol
Physical stateColourless, odourless gas
Solution chemistryCO₂ + H₂O → H₂CO₃ → HCO₃⁻ → CO₃²⁻; absorption rises steeply above pH 9.
Occupational limitsTypically 5 000 ppm TWA / 15 000 ppm STEL — verify against local regulation.
Typical sourcesCombustion, pyrolysis, fermentation, calcination and acid dosing of carbonate liquors.
Best analytical detectionNDIR — the reference method for CO₂ in flue gas: linear, robust and unaffected by water when the sample is conditioned. FTIR where CO₂ is measured alongside other species.

*Values are indicative and may vary by source. For safety and design, always consult current SDS and regulations.

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