Carbon Monoxide — properties & hazards overview

Name: Carbon monoxide Formula: CO CAS: 630-08-0 UN: 1016
DANGER — Odourless, colourless and acutely toxic: CO binds haemoglobin some 240× more strongly than oxygen, so there is no warning before collapse. Also flammable over a very wide range (12.5–74 vol%). CO is not removable by wet scrubbing — it needs oxidation.
Boiling point
−191.5 °C
Explosion limits (air)
12.5 – 74 vol%
Autoignition
≈ 605 °C
Water solubility
0.028 g/L (20 °C) — negligible
Toxicity
COHb; no odour warning
Flammability
12.5–74 vol%
Chronic risk
Hypoxic organ damage
Environmental
Ozone precursor
PropertyValue / Note
Chemical formulaCO
Molar mass28.01 g/mol
Physical stateColourless, odourless gas; density almost equal to air
ReactivityChemically inert towards water and alkali — it does not absorb. Oxidises to CO₂ over a catalyst or at high temperature.
Occupational limitsOrder of 20–30 ppm TWA / 100 ppm STEL — verify against local regulation.
Typical sourcesIncomplete combustion, pyrolysis and gasification (syngas), reduction furnaces, flares running rich.
Best analytical detectionNDIR for continuous stack measurement (the reference method), electrochemical cells for portable and safety detection, FTIR where CO is one of several species. CO is also the standard indicator for combustion quality.

*Values are indicative and may vary by source. For safety and design, always consult current SDS and regulations.

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