Proteins (aerosols & dust) — properties & hazards overview

Name: Proteins (various) General formula: (–NH–CHR–CO–)ₙ CAS: varies (mixture) UN: — (not classified as dangerous goods)
WARNING — Proteins are non-volatile: they appear in the gas stream as dust or as droplets carried over from a wet process, never as a vapour. The real issues are respiratory sensitisation, a very high COD load in the scrubber liquor, and the odour that follows once they start to decompose.
Volatility
Non-volatile (particulate / aerosol)
Water affinity
Soluble or colloidal; foams readily
Degradation products
NH₃, amines, H₂S, mercaptans
Environmental
Very high COD / BOD and nitrogen
Toxicity
Low acute toxicity
Flammability
Combustible dust when dry
Chronic risk
Respiratory sensitiser
Environmental
COD / N load; odour
PropertyValue / Note
CompositionPolymers of amino acids; in off-gas as fine dust from drying and milling, or as droplets from cooking, evaporating and spray-drying. See also the sheets Amino Acids and Enzymes.
Physical stateSolid particulate when dried; liquid aerosol when carried from a wet stage.
ReactivityDenature and coagulate with heat and pH shift — useful for recovery, but they also foul heat exchangers and packing.
Behaviour in a scrubberCaptured by impaction and dissolution. They foam persistently in the sump and feed rapid biological growth if the liquor is warm.
Typical sourcesPotato and vegetable processing, dairy and egg drying, offal and blood processing, fermentation and enzyme production.
Best analytical detectionIsokinetic gravimetric PM sampling for the emitted mass; total nitrogen (Kjeldahl) and COD in the liquor to quantify the captured load; olfactometry where decomposition odour is the complaint.

*Indicative values; verify specifics via SDS/process data. Enzyme-containing dusts are treated as respiratory sensitisers even at very low concentration.

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